An old chemistry demo: mercury with blue crystals in ampule

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An old chemistry demo: mercury with blue crystals in ampule

Postby mododavid » Fri Oct 07, 2011 11:45 pm UTC

I am an PhD student (emphasis in inorganic). I am currently working with a local high school chemistry teacher to put together lessons and go through all the stuff left behind by the very old chemistry teacher who retired. We found a large, sealed test tube (ampule) with mercury and some blue crystals in it (the crystals resemble pieces of cobalt glass). I've seen this before, but it was red crystals last time (I don't think they were cinnabar, but maybe.) I think it's used to demonstrate some chemical or physical properties. Beyond that, I'm clueless. Also, the old chemistry teacher, who was there for over 30 years, said that the tube was purchased by some teacher before she taught there. So, it's a very old demo, and I can't find it in any science teacher supply catalogs. Anybody have any idea? I have a pic, but I don't know how to post it here. Thanks for any help.
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Re: An old chemistry demo: mercury with blue crystals in am

Postby Magnesium24 » Wed Mar 28, 2012 12:14 am UTC

mododavid - I found one in my lab, just as you described. Have you figured out what it is yet?
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Re: An old chemistry demo: mercury with blue crystals in am

Postby jimsfriend » Wed Mar 28, 2012 8:10 pm UTC

I found this http://pubs.acs.org/doi/abs/10.1021/om00097a004
It mentions mercury and cobalt and red crystals. All things that are in the OP. Other than that I don't know anything about this. It could just be a demonstration of large mercury compound, but that sounds like a pretty boring demo :p
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Re: An old chemistry demo: mercury with blue crystals in am

Postby ikrase » Wed Apr 04, 2012 5:39 am UTC

Are you sure that it was mercury? What you describe sounds vaguely like N204 tubes that were in my high school chem lab.
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Re: An old chemistry demo: mercury with blue crystals in am

Postby Magnesium24 » Wed Apr 04, 2012 9:07 am UTC

This one seems to be mercury. I found two N2O4 tubes as well.
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Re: An old chemistry demo: mercury with blue crystals in am

Postby Magnesium24 » Fri Jun 08, 2012 2:33 am UTC

Finally took a picture of the ampule. Still no idea what it is. No response to heat (65 degrees C) or blacklight (395 nm).

http://www.flickr.com/photos/64213337@N07/7350206338/in/photostream
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Re: An old chemistry demo: mercury with blue crystals in am

Postby PM 2Ring » Fri Jun 08, 2012 4:37 am UTC

Those blue "crystals" look suspiciously like Blue Indicating Silica Gel. I don't know what they're doing in a sealed ampule containing mercury, though I guess they'd prevent hydroxide formation, keeping the mercury surface nice and shiny.
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